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• W1973936250 abstract "Using Fe3(CO)12 as the catalyst, the reaction of styrenes (C6H5CHCH2, p-CH3C6H4CHCH2, p- ClC6H4CHCH2, and p-CH3OC6H4CHCH2) with triethyisilane gave (E)-β-(triethylsilyl)styrenes (2a, (E)-C6H5CHCHSiEt3; 2b, (E)-p-CH3C6H4CHCHSiEt3; 2c, (E)-p-ClC 6H4CHCHSiEt3; 2d, (E)-p-CH3OC6H4CHCHSiEt3) in 66–89% yields with complete selectivity. Similarly, Fe2(CO)9 also catalyzed dehydrogenative silylation again, with complete selectivity but in low yields. The reaction of styrene with treithylsilane, catalysed by OS3(CO)12, gave a mixture of the corresponding vinylsilane (dehydrogenative silylation product) and alkylsilane (hydrosilylation product)." @default.
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• W1973936250 date "1993-08-01" @default.
• W1973936250 modified "2023-09-26" @default.
• W1973936250 title "Completely selective synthesis of (E)-β-(triethylsilyl) styrenes by Fe3(CO)12-catalyzed reaction of styrenes with triethylsilane" @default.
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• W1973936250 doi "https://doi.org/10.1016/0022-328x(93)83315-m" @default.
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