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- W1973988082 abstract "A model is presented for the distribution of photochemically active gases in and above the upper cloud layer of Venus. Attention is focused on reproducing the experimental results of the Pioneer Venus (PV) mission, especially the ultraviolet spectrometer results for the cloud top SO 2 distribution. The reconciliation of these results with the photochemical oxidation and hydration of SO 2 into sulfuric acid aerosol puts limits on the vertical mixing rates in this region, with a value of K around 2 × 10 4 cm²s −1 being preferred. A model with SO 2 being the major sulfur bearing gas is consistent with the PV measurements. The measured SO 2 is more than ample to produce the observed H 2 SO 4 in the upper cloud region and balance the sulfur budget in this region. The ClO x chemistry above the clouds and the relatively large SO 2 concentration in the cloud top region suppresses the odd hydrogen density and thus inhibits the catalyzed recombination of O 2 with CO to form CO 2 . In conjunction with the slow eddy mixing, this leads to O 2 mixing ratios at the cloud tops that are much larger than earth‐based measurements; however, the major features of our sulfur model are not dependent on the O 2 abundance." @default.
- W1973988082 created "2016-06-24" @default.
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- W1973988082 date "1980-12-30" @default.
- W1973988082 modified "2023-10-13" @default.
- W1973988082 title "Photochemistry of SO<sub>2</sub> in Venus' upper cloud layers" @default.
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- W1973988082 doi "https://doi.org/10.1029/ja085ia13p07849" @default.
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