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• W1973999993 abstract "The linear viscoelasticity of polymers near the gel point can be described by two scaling laws. The material at the gel point has a power-law linear viscoelastic relaxation modulus, and the relaxation exponent has been found to vary with the composition of the precursor materials, i.e., it is not universal for gelation. A second scaling law describes the evolution of the linear viscoelastic properties through the gel point. The rate of change of the dynamic mechanical modulus/viscosity is observed to scale as a power-law function of frequency. This power-law function defines a dynamic critical exponent, and this has been found to be independent of precursor composition for end-linking poly(dimethylsiloxane) polymers and equal to κ = 0.21 ± 0.02. This exponent may be a universal measure of gelation. The technique of Time Resolved Mechanical Spectroscopy is used to observe the evolution of linear viscoelastic properties of crosslinking polymers in situ in the rheometer. A stretched exponential relaxation modulus describes the evolution of mechanical properties in the vicinity of the gel point very well. The exponents which characterize the divergence of the zero-shear viscosity and the equilibrium modulus are not universal, since they are related to the relaxation exponent and the dynamic critical exponent." @default.
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• W1973999993 date "1991-05-01" @default.
• W1973999993 modified "2023-09-26" @default.
• W1973999993 title "The evolution of viscoelasticity near the gel point of end-linking poly(dimethylsiloxane)s" @default.
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• W1973999993 doi "https://doi.org/10.1002/masy.19910450105" @default.
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