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• W1974014730 endingPage "A477" @default.
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• W1974014730 abstract "We produced a novel conducting polymer electrolyte and added a poly(ethylene glycol) (PEG)-borate ester as a new type plasticizer having a Lewis acidity and investigated the influence of the Lewis acidity of the PEG-borate ester to a solid polymer electrolyte containing salt. Adding the PEG-borate ester into the electrolyte shows the increase in the ionic conductivity of the polymer electrolyte. By measuring the glass transition temperature of the polymer electrolytes using differential scanning calorimetry, it became clear that the mobility of the carrier ion increases with increasing the amount of the PEG-borate ester. By investigating the temperature dependence of the ionic conductivity using William-Landel-Ferry type equation and measuring Raman spectra of the polymer electrolytes, it was found that the concentration of the carrier ion increases with increasing the amount of the PEG-borate ester in the polymer electrolyte. Furthermore, by estimating the transference number of the cation and performing the ab initio calculation for the PEG-borate ester, it is suggested that the PEG-borate ester may enhance the degree of dissociation of the Mg salt in the polymer electrolyte to increase the ratio of the free ion, especially by interacting with and trapping the anion of the salt as a Lewis acid. © 2003 The Electrochemical Society. All rights reserved." @default.
• W1974014730 created "2016-06-24" @default.
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• W1974014730 date "2003-01-01" @default.
• W1974014730 modified "2023-10-17" @default.
• W1974014730 title "Influence of PEG-Borate Ester as a Lewis Acid on Ionic Conductivity of Polymer Electrolyte Containing Mg-Salt" @default.
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• W1974014730 doi "https://doi.org/10.1149/1.1559066" @default.
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