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- W1974053519 abstract "Polyoxymethylene dimethyl ethers (PODEn or DMMn) were synthesized by the condensation of methanol and trioxymethylene over the catalysts of several molecular sieves like HY, HZSM-5, Hβ, and HMCM-22; the effect of their acidic properties on product distribution was investigated. The results indicated that the acidic molecular sieves, especially HMCM-22, are catalytically active for the condensation of methanol and trioxymethylene to form DMMn. Over HY, the main product is dimethoxymethane (DMM), with a selectivity of 92.87%. Over HZSM-5 and Hβ, the main products turn out to be DMM1-3 and the yields of DMM3-8, which are ideal additives for diesel fuel, reach 6.40% and 13.78%, respectively. With HMCM-22 as the catalyst, the formation of long chain DMMn products is further enhanced and the yield of DMM3-8 attains 29.39%. The results of NH3-TPD demonstrated that the product distribution is related to the surface acidic properties of the catalyst used; short chain DMM may be primarily formed on weak acidic sites, while the acidic sites of medium strength can enhance the formation of diesel fuel additive components DMM3-8." @default.
- W1974053519 created "2016-06-24" @default.
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- W1974053519 date "2011-12-01" @default.
- W1974053519 modified "2023-10-16" @default.
- W1974053519 title "Synthesis of polyoxymethylene dimethyl ethers from methanol and trioxymethylene with molecular sieves as catalysts" @default.
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- W1974053519 doi "https://doi.org/10.1016/s1872-5813(12)60003-6" @default.
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