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- W1974060467 abstract "Abstract In this paper the CF bond activation of polyfluoroaryl imines is explored at cobalt(0) center with an imine‐N atom as an anchoring group. The reaction of F 5 C 6 ‐CHN‐(2′‐ClC 6 H 4 ) ( 2 ) and F 5 C 6 ‐CHN‐C 6 H 5 ( 3 ) with Co(PMe 3 ) 4 afforded the CF bond activation products ( ortho ‐F 4 C 6 ‐CHN‐(2′‐ClC 6 H 4 ))Co(I)(PMe 3 ) 3 ( 5 ) and ( ortho ‐F 4 C 6 ‐CHN‐C 6 H 5 )Co(II)(F)(PMe 3 ) 2 ( 6 ), while only π‐(CN) coordinated cobalt(0) complex (2,4,5‐F 3 C 6 H 2 ‐CHN‐(4′‐ClC 6 H 4 ))Co(0)(PMe 3 ) 3 ( 4 ) was obtained from 2,4,5‐F 3 C 6 H 2 ‐CHN‐(4′‐ClC 6 H 4 ) ( 1 ) without CF bond activation. Complexes 4 – 6 were characterized through X‐ray single crystal diffraction. It was also found that dialkylation of N ‐(perfluorobenzylidene)benzenamine with organozinc reagents could be catalyzed by Co(PMe 3 ) 4 via C,C‐coupling reaction under mild conditions." @default.
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- W1974060467 date "2013-07-01" @default.
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- W1974060467 title "Cobalt-catalyzed Selective CF Bond Activation and Alkylation of Polyfluoroaryl Imines" @default.
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- W1974060467 doi "https://doi.org/10.1002/cjoc.201300340" @default.
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