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- W1974070537 abstract "The reaction of diazoindene (C9H6N2) with [Ru3(CO)12] in THF leads to the formation of the clusters [Ru3(CO)10(η5:η1-C9H6)] (1), by the insertion of a C9H6 moiety into a Ru−Ru bond, [Ru3(CO)8(η5-C9H6)2] (2), a trinuclear complex with an open Ru3 unit containing the 1,1‘-bis(indenylidene) ligand, and two metallacyclic ruthenium trimers of formula [Ru3(CO)6(η5:η1-C9H6)3] (3 and 4). The cyclic trimers have stable chair- and twist-boat-like configurations similar to the boat−chair isomerism of cyclohexane. Both complexes are configurational rather than conformational isomers, because the boat-to-chair ring flip is hampered by the rigid nature of the Ru3C3 metallacycle. The structures of 2−4 have been established by X-ray crystallography." @default.
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- W1974070537 title "Synthesis and Molecular Structure of Two Six-Membered Ru<sub>3</sub>C<sub>3</sub> Rings Existing in Boat- and Chairlike Configurations Formed by Insertion of C<sub>9</sub>H<sub>6</sub> Units into Metal−Metal Bonds of [Ru<sub>3</sub>(CO)<sub>12</sub>]" @default.
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- W1974070537 doi "https://doi.org/10.1021/om9600102" @default.
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