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- W1974077536 abstract "The antitumor agent (−)-rhazinilam was synthesized in three major steps, namely the pyrrole synthesis, selective C−H bond activation, and direct macrolactam formation. The key step involved asymmetric C−H bond functionalization (dehydrogenation) of the diethyl group segment in intermediate 6. This was achieved by the attachment of chiral platinum complexes to the proximal nitrogen atom. A high degree of selectivity (60−75% ee) was achieved via the use of oxazolinyl ketone chiral auxiliaries." @default.
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- W1974077536 date "2002-05-23" @default.
- W1974077536 modified "2023-10-14" @default.
- W1974077536 title "Total Synthesis of (−)-Rhazinilam: Asymmetric C−H Bond Activation via the Use of a Chiral Auxiliary" @default.
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- W1974077536 doi "https://doi.org/10.1021/ja026130k" @default.
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