FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1974092511> ?p ?o ?g. }

• W1974092511 endingPage "295" @default.
• W1974092511 startingPage "288" @default.
• W1974092511 abstract "Steady-state and time-resolved fluorescence measurements were used to study the relaxation of the microenvironment of hydrophobic probes 6-propionyl-2-(dimethylamino)naphthalene (prodan) and 6-dodecanoyl-2-(dimethylamino)naphthalene (laurdan) in systems containing vesicles formed by the amphiphilic diblock copolymer poly(ε-caprolactone)-block-poly(ethylene oxide) (PCL-PEO) and water/tetrahydrofurane (THF) solvent mixtures. It was found that in case of prodan, both steady-state and time-resolved emission spectra were composed of two subspectra corresponding to the emission of prodan molecules located (i) in fairly rigid (effectively viscous) and hydrophobic domains of the vesicles close to the PCL/PEO interface and (ii) in a more polar and less viscous medium (in the bulk solution). The fraction of the emission from the more polar microenvironment increases with increasing content of THF in the system. Laurdan, in contrast to prodan, appeared to be solubilized preferentially in the hydrophobic domains up to 30 vol % of THF content, and its emission spectra changed only due to swelling of hydrophobic PCL domains by added THF. The study shows that the analysis of the time-resolved emission from a probe distributed in two media is, in principle, possible, but it is quite complex and appreciably less accurate, and the relaxation times are ill-defined averages of several processes. The bimodal or shoulder-containing time-resolved spectra have to be decomposed in pertinent time-resolved subspectra and treated separately. Another important result of the study is a piece of knowledge concerning the motion of the probe with respect to the vesicle. In the studied complex system, not only the relaxation of the solvent and reorganization of polymer segments around the fluorescent headgroup of the probe affect the emission but also a lateral motion of the probe with respect to the nanoparticle within the lifetime of the excited state contributes significantly to the relaxation and to the relatively slow time-resolved Stokes shift." @default.
• W1974092511 created "2016-06-24" @default.
• W1974092511 creator A5000467636 @default.
• W1974092511 creator A5010915275 @default.
• W1974092511 creator A5020938137 @default.
• W1974092511 creator A5040301857 @default.
• W1974092511 creator A5077703445 @default.
• W1974092511 date "2007-11-29" @default.
• W1974092511 modified "2023-09-24" @default.
• W1974092511 title "Fluorescence Study of the Solvation of Fluorescent Probes Prodan and Laurdan in Poly(ε-caprolactone)-<i>block</i>-poly(ethylene oxide) Vesicles in Aqueous Solutions with Tetrahydrofurane" @default.
• W1974092511 cites W1229372959 @default.
• W1974092511 cites W1496849733 @default.
• W1974092511 cites W1966234921 @default.
• W1974092511 cites W1968467952 @default.
• W1974092511 cites W1969143715 @default.
• W1974092511 cites W1970956558 @default.
• W1974092511 cites W1972670975 @default.
• W1974092511 cites W1977619408 @default.
• W1974092511 cites W1977887028 @default.
• W1974092511 cites W1978679905 @default.
• W1974092511 cites W1981039423 @default.
• W1974092511 cites W1983673489 @default.
• W1974092511 cites W1996144108 @default.
• W1974092511 cites W2000135711 @default.
• W1974092511 cites W2004351146 @default.
• W1974092511 cites W2005400901 @default.
• W1974092511 cites W2006978357 @default.
• W1974092511 cites W2019686328 @default.
• W1974092511 cites W2022958344 @default.
• W1974092511 cites W2024352529 @default.
• W1974092511 cites W2029479259 @default.
• W1974092511 cites W2030794360 @default.
• W1974092511 cites W2031819592 @default.
• W1974092511 cites W2035351582 @default.
• W1974092511 cites W2040584889 @default.
• W1974092511 cites W2052942629 @default.
• W1974092511 cites W2054947925 @default.
• W1974092511 cites W2079164370 @default.
• W1974092511 cites W2122460128 @default.
• W1974092511 doi "https://doi.org/10.1021/la702277t" @default.
• W1974092511 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18044937" @default.
• W1974092511 hasPublicationYear "2007" @default.
• W1974092511 type Work @default.
• W1974092511 sameAs 1974092511 @default.
• W1974092511 citedByCount "34" @default.
• W1974092511 countsByYear W19740925112012 @default.
• W1974092511 countsByYear W19740925112013 @default.
• W1974092511 countsByYear W19740925112014 @default.
• W1974092511 countsByYear W19740925112015 @default.
• W1974092511 countsByYear W19740925112016 @default.
• W1974092511 countsByYear W19740925112017 @default.
• W1974092511 countsByYear W19740925112019 @default.
• W1974092511 countsByYear W19740925112020 @default.
• W1974092511 countsByYear W19740925112021 @default.
• W1974092511 countsByYear W19740925112022 @default.
• W1974092511 countsByYear W19740925112023 @default.
• W1974092511 crossrefType "journal-article" @default.
• W1974092511 hasAuthorship W1974092511A5000467636 @default.
• W1974092511 hasAuthorship W1974092511A5010915275 @default.
• W1974092511 hasAuthorship W1974092511A5020938137 @default.
• W1974092511 hasAuthorship W1974092511A5040301857 @default.
• W1974092511 hasAuthorship W1974092511A5077703445 @default.
• W1974092511 hasConcept C113196181 @default.
• W1974092511 hasConcept C121332964 @default.
• W1974092511 hasConcept C127413603 @default.
• W1974092511 hasConcept C130316041 @default.
• W1974092511 hasConcept C148093993 @default.
• W1974092511 hasConcept C15920480 @default.
• W1974092511 hasConcept C178790620 @default.
• W1974092511 hasConcept C184651966 @default.
• W1974092511 hasConcept C185592680 @default.
• W1974092511 hasConcept C2777801237 @default.
• W1974092511 hasConcept C2778390148 @default.
• W1974092511 hasConcept C2780471494 @default.
• W1974092511 hasConcept C41625074 @default.
• W1974092511 hasConcept C42360764 @default.
• W1974092511 hasConcept C521977710 @default.
• W1974092511 hasConcept C55493867 @default.
• W1974092511 hasConcept C62520636 @default.
• W1974092511 hasConcept C75473681 @default.
• W1974092511 hasConcept C91881484 @default.
• W1974092511 hasConceptScore W1974092511C113196181 @default.
• W1974092511 hasConceptScore W1974092511C121332964 @default.
• W1974092511 hasConceptScore W1974092511C127413603 @default.
• W1974092511 hasConceptScore W1974092511C130316041 @default.
• W1974092511 hasConceptScore W1974092511C148093993 @default.
• W1974092511 hasConceptScore W1974092511C15920480 @default.
• W1974092511 hasConceptScore W1974092511C178790620 @default.
• W1974092511 hasConceptScore W1974092511C184651966 @default.
• W1974092511 hasConceptScore W1974092511C185592680 @default.
• W1974092511 hasConceptScore W1974092511C2777801237 @default.
• W1974092511 hasConceptScore W1974092511C2778390148 @default.
• W1974092511 hasConceptScore W1974092511C2780471494 @default.
• W1974092511 hasConceptScore W1974092511C41625074 @default.
• W1974092511 hasConceptScore W1974092511C42360764 @default.
• W1974092511 hasConceptScore W1974092511C521977710 @default.
• W1974092511 hasConceptScore W1974092511C55493867 @default.
• W1974092511 hasConceptScore W1974092511C62520636 @default.

• next