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- W1974098126 abstract "The mutual solubilities of thorium and lanthanum, neodymium, or europium in bismuth solution have been determined over the temperature range 350–700 °C. Thorium and each lanthanide (Ln), dissolved in liquid bismuth, were found to interact to produce a solid compound with the apparent composition ThLnBiy. The variation of the mole fraction solubility products with temperature can be expressed as log Ksp = log(NThNLn) = 2.410–6480/T(K) for ThLaBiy and log Ksp = 3.233–7285/T(K) for ThNdBiy. The standard free energies of formation for ThLaBiy and ThNdBiy were estimated to be about (−114.8 + 0.0208T) and (−99.8 + 0.0207T) kcal/mole, respectively. The solubility of europium in bismuth was determined over the temperature range 350–550 °C. The data can be represented by the expression : log SEu (wt.%) = 4.4823-2973/T(K)." @default.
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- W1974098126 date "1972-09-01" @default.
- W1974098126 modified "2023-10-18" @default.
- W1974098126 title "Mutual interactions of thorium, lanthanides, and bismuth in Th-Ln-Bi solutions: Evidence for the formation of ThLnBiy compounds" @default.
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- W1974098126 doi "https://doi.org/10.1016/0022-5088(72)90148-8" @default.
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