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- W1974134497 abstract "A theoretical description of the origin of the several types of forbidden cross peaks encountered in two-dimensional double-quantum spectra of AX3 spin systems in macromolecules is presented. We present a double-quantum data set for a small protein, acyl carrier protein (ACP), and focus on the seven alanine residues found in ACP. An analysis of the forbidden peaks associated with the alanine residues and threonine-2 indicates that the carboxyl terminus of the protein is much more flexible than the amino terminus. We discuss how an understanding of methyl group dynamics obtained from such spectra can aid in the correct interpretation of NOE cross peaks involving these groups in terms of internuclear distances." @default.
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- W1974134497 date "1988-01-01" @default.
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- W1974134497 title "AX3 spin system dynamics from forbidden cross peaks in double-quantum two-dimensional NMR experiments, with application to acyl carrier protein" @default.
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- W1974134497 doi "https://doi.org/10.1016/0022-2364(88)90198-9" @default.
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