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- W1974165116 abstract "The (2E,4E)- and (2E,4Z)-1-phenyl-1,6-dioxo-hepta-2,4-diene reacts with aziridine to give aziridinecyclopentenol 3. This product arises from an intermolecular Michael addition of a nitrogen lone pair to the less reactive enone, followed by an intramolecular aldol reaction of the enol with ketone. Furthermore, the initially formed enol did not undergo nucleophilic attack onto the aziridine ring to form heterocycles. Interestingly, the reaction with secondary amine did not give the cyclopentenol adduct, and this only leads to the isomerization of (2E,4Z)-1-phenyl-1,6-dioxo-hepta-2,4-diene to the more stable (2E,4E)-1-phenyl-1,6-dioxo-hepta-2,4-diene by addition to the more reactive enone." @default.
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- W1974165116 date "2007-12-01" @default.
- W1974165116 modified "2023-10-03" @default.
- W1974165116 title "Reaction of 1,6-Dioxo-2,4-Diene with Aziridine and Secondary Amine" @default.
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- W1974165116 doi "https://doi.org/10.1002/jccs.200700225" @default.
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