Matches in SemOpenAlex for { <https://semopenalex.org/work/W1974172158> ?p ?o ?g. }
- W1974172158 endingPage "636" @default.
- W1974172158 startingPage "621" @default.
- W1974172158 abstract "Various porphyrin–fullerene-linked systems have been prepared to elucidate the intrinsic electron-transfer properties of fullerenes. Photodynamical studies on porphyrin–fullerene-linked systems showed that spherical fullerenes accelerated photoinduced electron transfer and charge-shift, but slowed down charge recombination, which is in sharp contrast with those of conventional planar acceptors such as quinones and imides. For the first time, it was shown that the unique electron-transfer properties result from the small reorganization energies of fullerenes arising from the delocalized π system on the sphere together with the rigid structure. The small reorganization energies make it possible to produce a long-lived charge-separated state with a high quantum yield in donor–fullerene systems. The finding also will allow us to construct light energy conversion systems as well as artificial photosynthetic models. Highly efficient photoinduced energy and electron transfer were achieved on gold and ITO electrodes modified with self-assembled monolayers of the porphyrin–fullerene-linked systems. We also developed dye-sensitized bulk heterojunction solar cell possessing both characteristics of dye-sensitized and bulk heterojunction solar cells. These results showed the advantages of fullerenes as electron acceptors in artificial photosynthetic model, photonic molecular devices and machines, and organic molecular electronics including solar cells." @default.
- W1974172158 created "2016-06-24" @default.
- W1974172158 creator A5044564540 @default.
- W1974172158 date "2007-04-15" @default.
- W1974172158 modified "2023-09-30" @default.
- W1974172158 title "Creation of Fullerene-Based Artificial Photosynthetic Systems" @default.
- W1974172158 cites W12334191 @default.
- W1974172158 cites W1530818404 @default.
- W1974172158 cites W1568680237 @default.
- W1974172158 cites W1591883199 @default.
- W1974172158 cites W1661851364 @default.
- W1974172158 cites W1906835478 @default.
- W1974172158 cites W1963645330 @default.
- W1974172158 cites W1965058351 @default.
- W1974172158 cites W1968194371 @default.
- W1974172158 cites W1970897945 @default.
- W1974172158 cites W1972060646 @default.
- W1974172158 cites W1972256033 @default.
- W1974172158 cites W1973201534 @default.
- W1974172158 cites W1975049557 @default.
- W1974172158 cites W1976036521 @default.
- W1974172158 cites W1976545896 @default.
- W1974172158 cites W1977378281 @default.
- W1974172158 cites W1977431122 @default.
- W1974172158 cites W1978544868 @default.
- W1974172158 cites W1980216394 @default.
- W1974172158 cites W1981817777 @default.
- W1974172158 cites W1982111271 @default.
- W1974172158 cites W1985367975 @default.
- W1974172158 cites W1985538401 @default.
- W1974172158 cites W1989037764 @default.
- W1974172158 cites W1990113942 @default.
- W1974172158 cites W1990447507 @default.
- W1974172158 cites W1991615073 @default.
- W1974172158 cites W1992275488 @default.
- W1974172158 cites W1992998423 @default.
- W1974172158 cites W1994596848 @default.
- W1974172158 cites W1995042186 @default.
- W1974172158 cites W1995941759 @default.
- W1974172158 cites W1996291528 @default.
- W1974172158 cites W1996360325 @default.
- W1974172158 cites W1997318959 @default.
- W1974172158 cites W1998549904 @default.
- W1974172158 cites W1999424409 @default.
- W1974172158 cites W1999777680 @default.
- W1974172158 cites W2000776563 @default.
- W1974172158 cites W2001236753 @default.
- W1974172158 cites W2002024849 @default.
- W1974172158 cites W2002901794 @default.
- W1974172158 cites W2003398929 @default.
- W1974172158 cites W2003923730 @default.
- W1974172158 cites W2003933134 @default.
- W1974172158 cites W2006144699 @default.
- W1974172158 cites W2008243507 @default.
- W1974172158 cites W2008878534 @default.
- W1974172158 cites W2009167923 @default.
- W1974172158 cites W2010790991 @default.
- W1974172158 cites W2011344355 @default.
- W1974172158 cites W2013543704 @default.
- W1974172158 cites W2014394792 @default.
- W1974172158 cites W2014783383 @default.
- W1974172158 cites W2015073555 @default.
- W1974172158 cites W2015240500 @default.
- W1974172158 cites W2017389771 @default.
- W1974172158 cites W2018580792 @default.
- W1974172158 cites W2019931240 @default.
- W1974172158 cites W2022855480 @default.
- W1974172158 cites W2023267632 @default.
- W1974172158 cites W2023544689 @default.
- W1974172158 cites W2024471326 @default.
- W1974172158 cites W2024595175 @default.
- W1974172158 cites W2026714209 @default.
- W1974172158 cites W2028050914 @default.
- W1974172158 cites W2028416984 @default.
- W1974172158 cites W2028772401 @default.
- W1974172158 cites W2031686744 @default.
- W1974172158 cites W2031697017 @default.
- W1974172158 cites W2031904472 @default.
- W1974172158 cites W2032238744 @default.
- W1974172158 cites W2033107693 @default.
- W1974172158 cites W2034311513 @default.
- W1974172158 cites W2035025222 @default.
- W1974172158 cites W2035569224 @default.
- W1974172158 cites W2039719857 @default.
- W1974172158 cites W2040461143 @default.
- W1974172158 cites W2042189779 @default.
- W1974172158 cites W2042950898 @default.
- W1974172158 cites W2043649459 @default.
- W1974172158 cites W2044879769 @default.
- W1974172158 cites W2045088626 @default.
- W1974172158 cites W2046049711 @default.
- W1974172158 cites W2046295231 @default.
- W1974172158 cites W2047333772 @default.
- W1974172158 cites W2047616133 @default.
- W1974172158 cites W2047721111 @default.
- W1974172158 cites W2048067383 @default.
- W1974172158 cites W2048508129 @default.
- W1974172158 cites W2049745418 @default.