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- W1974183245 abstract "The hydrolytic reaction of diazepam in acid solution at body temperature was studied spectrophotometrically. The reversible azomethine bond cleavage reaction of diazepam took place and an open-ring compound was in equilibrium with a closed-ring compound (protonated diazepam) The rate of ring closure was found to be greater than that of ring-opening, indicating that the concentration at equilibrium of the closed-ring compound is larger than the open-ring species. The activation energies of the forward and reverse reactions were obtained from Arrhenius type plots. In addition, the effect of pH on these reactions was examined." @default.
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- W1974183245 date "1979-09-01" @default.
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- W1974183245 title "Reversible ring-opening reaction of diazepam in acid media around body temperature" @default.
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- W1974183245 doi "https://doi.org/10.1016/0378-5173(79)90003-6" @default.
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