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- W1974245021 abstract "Dialkyl ethenephosphonates, on reaction with aryl bromides in the presence of palladium catalyst, gave the corresponding 2-arylethenephosphonates (6 or 7) in moderate to good yields. Thus, it provides a simple and facile synthesis of 2-arylethenephosphonates. Their 31P-NMR chemical shifts show a linear correlation with the Hammett σ constants of the substituents in the benzene ring. Similarly, diethyl ethenephosphonate underwent palladium-catalyzed vinylation reaction with vinyl bromides and the corresponding substituted 1,3-dienephosphonates (10) were formed, though in less satisfactory yields. The configurations of compounds 6, 7 and 10 were determined by NMR spectroscopy." @default.
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- W1974245021 date "1985-09-01" @default.
- W1974245021 modified "2023-09-28" @default.
- W1974245021 title "Palladium-catalyzed arylation and vinylation of dialkyl ethenephosphonates" @default.
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- W1974245021 doi "https://doi.org/10.1002/cjoc.19850030314" @default.
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