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- W1974342955 abstract "Reactions of decaborane nido-B10H14 with a series of fluorobenzaldehydes in alkaline solution followed by treatment with iodine give the closo-[2-(X-FC6H4)-2-CB9H9]− anions (X = 2, 3, 4). Upon heating, these compounds rearrange to more thermodynamically stable closo-[1-(X-FC6H4)-1-CB9H9]− anions (X = 2, 3, 4). The compounds synthesized were characterized by multinuclear NMR spectroscopy. The crystal structures of (Bu4N)[1-(2-FC6H4)-1-CB9H9] and (Bu4N)2[2-(4-FC6H4)-2-CB9H9][1-(4-FC6H4)-1-CB9H9] were determined by single crystal X-ray diffraction." @default.
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- W1974342955 date "2012-10-01" @default.
- W1974342955 modified "2023-10-05" @default.
- W1974342955 title "Synthesis and structure of fluorophenyl derivatives of the 10-vertex monocarbaborane anions [1-CB9H10]− and [2-CB9H10]−" @default.
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- W1974342955 doi "https://doi.org/10.1016/j.jfluchem.2012.06.019" @default.
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