Matches in SemOpenAlex for { <https://semopenalex.org/work/W1974348528> ?p ?o ?g. }
- W1974348528 endingPage "7865" @default.
- W1974348528 startingPage "7858" @default.
- W1974348528 abstract "We report new osmium complexes based upon the 2-[(diphenylphosphanyl)-methyl]-pyridine ligand. Hexafluorophosphate salts of bis(3,4,7,8-tetramethyl-1,10-phenantholine)(2-[(diphenylphosphanyl)-methyl]-pyridine)osmium(II) (1), and bis(2-[(diphenylphosphanyl)-methyl]-pyridine)(4,7-diphenyl-1,10-phenantholine)osmium(II) (2) have been synthesized, and X-ray structures have been obtained. Indexing and unit cell refinement of both 1 and 2 indicated a monoclinic P lattice. The space groups were found to be P1̅ (No. 2) and P21/c, respectively. Both 1 and 2 were found to have the same emission at 645 nm despite the differences in structure. Through density functional theory (DFT) calculations we were able to conclude that the highest occupied molecular orbital (HOMO) of the complexes is the dxy orbital on the osmium, while the lowest unoccupied molecular orbital (LUMO) is the b1(Ψ)π* system of the phenanthroline. However, we found that dxy did not have the correct orientation to enable charge transfer to the phenanthroline, and the actual metal-to-ligand charge transfer (MLCT) transition is dxz (HOMO-1) to the π* LUMO of the phenanthroline." @default.
- W1974348528 created "2016-06-24" @default.
- W1974348528 creator A5003368942 @default.
- W1974348528 creator A5032276351 @default.
- W1974348528 creator A5039612081 @default.
- W1974348528 creator A5051464355 @default.
- W1974348528 date "2008-05-01" @default.
- W1974348528 modified "2023-09-26" @default.
- W1974348528 title "Complexes of Osmium with the 2-[(Diphenylphosphanyl)-methyl]-pyridine Ligand" @default.
- W1974348528 cites W1911304003 @default.
- W1974348528 cites W1957306131 @default.
- W1974348528 cites W1964395868 @default.
- W1974348528 cites W1968545719 @default.
- W1974348528 cites W1969609411 @default.
- W1974348528 cites W1971587430 @default.
- W1974348528 cites W1975582705 @default.
- W1974348528 cites W1977535094 @default.
- W1974348528 cites W1980073283 @default.
- W1974348528 cites W1981368803 @default.
- W1974348528 cites W1984895575 @default.
- W1974348528 cites W1985385070 @default.
- W1974348528 cites W1985396835 @default.
- W1974348528 cites W1987648797 @default.
- W1974348528 cites W1993252622 @default.
- W1974348528 cites W1993940760 @default.
- W1974348528 cites W1994927385 @default.
- W1974348528 cites W1998151266 @default.
- W1974348528 cites W2000614287 @default.
- W1974348528 cites W2005259284 @default.
- W1974348528 cites W2005286482 @default.
- W1974348528 cites W2006695018 @default.
- W1974348528 cites W2013544484 @default.
- W1974348528 cites W2014144634 @default.
- W1974348528 cites W2014155554 @default.
- W1974348528 cites W2014731464 @default.
- W1974348528 cites W2015927589 @default.
- W1974348528 cites W2019810318 @default.
- W1974348528 cites W2020519739 @default.
- W1974348528 cites W2021532281 @default.
- W1974348528 cites W2022937304 @default.
- W1974348528 cites W2023900051 @default.
- W1974348528 cites W2024088828 @default.
- W1974348528 cites W2028897522 @default.
- W1974348528 cites W2030791051 @default.
- W1974348528 cites W2031195486 @default.
- W1974348528 cites W2031452130 @default.
- W1974348528 cites W2032647209 @default.
- W1974348528 cites W2034150875 @default.
- W1974348528 cites W2034791420 @default.
- W1974348528 cites W2034858040 @default.
- W1974348528 cites W2036323169 @default.
- W1974348528 cites W2039273708 @default.
- W1974348528 cites W2043114948 @default.
- W1974348528 cites W2043390423 @default.
- W1974348528 cites W2045928627 @default.
- W1974348528 cites W2047046225 @default.
- W1974348528 cites W2049691424 @default.
- W1974348528 cites W2050939175 @default.
- W1974348528 cites W2052329392 @default.
- W1974348528 cites W2053627938 @default.
- W1974348528 cites W2059020082 @default.
- W1974348528 cites W2066422982 @default.
- W1974348528 cites W2072515914 @default.
- W1974348528 cites W2074623710 @default.
- W1974348528 cites W2075148912 @default.
- W1974348528 cites W2076571784 @default.
- W1974348528 cites W2076984688 @default.
- W1974348528 cites W2084518995 @default.
- W1974348528 cites W2085853766 @default.
- W1974348528 cites W2086705003 @default.
- W1974348528 cites W2087562514 @default.
- W1974348528 cites W2091927025 @default.
- W1974348528 cites W2096269291 @default.
- W1974348528 cites W2097858436 @default.
- W1974348528 cites W2118077786 @default.
- W1974348528 cites W2120939781 @default.
- W1974348528 cites W2127765271 @default.
- W1974348528 cites W2146860717 @default.
- W1974348528 cites W2146942004 @default.
- W1974348528 cites W2151003442 @default.
- W1974348528 cites W2158294150 @default.
- W1974348528 cites W2372012729 @default.
- W1974348528 cites W2878404963 @default.
- W1974348528 cites W2952131195 @default.
- W1974348528 doi "https://doi.org/10.1021/jp711522d" @default.
- W1974348528 hasPublicationYear "2008" @default.
- W1974348528 type Work @default.
- W1974348528 sameAs 1974348528 @default.
- W1974348528 citedByCount "10" @default.
- W1974348528 countsByYear W19743485282012 @default.
- W1974348528 countsByYear W19743485282016 @default.
- W1974348528 countsByYear W19743485282020 @default.
- W1974348528 countsByYear W19743485282021 @default.
- W1974348528 crossrefType "journal-article" @default.
- W1974348528 hasAuthorship W1974348528A5003368942 @default.
- W1974348528 hasAuthorship W1974348528A5032276351 @default.
- W1974348528 hasAuthorship W1974348528A5039612081 @default.
- W1974348528 hasAuthorship W1974348528A5051464355 @default.