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- W1974396710 abstract "Reduction of Cl2Si[(NR)2C6H4-1,2] (R = CH2But) with potassium is known to lead to the stable silylene Si[(NR)2C6H4-1,2] (1). However, silylene 1 is now shown to react further with an alkali metal (Na or K) to yield the (1)22−, c-(1)3−˙, c-(1)32− or c-(1)42− derivatives. Reduction of Cl2Si[(NR)2C6H4-1,2] (R = CH2CH3 or CH2CHMe2) with potassium does not lead to an isolable silylene, but such a silylene is proposed to be an intermediate and, as for 1, reacts further to afford the potassium salts of c-[Si{(NR)2C6H4-1,2}]4−˙ and c-[Si{(NR)2C6H4-1,2}]42−. The pathways leading to the anionic cyclotri- and cyclotetrasilanes are discussed and supported experimentally; including by X-ray structures of relevant intermediates." @default.
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- W1974396710 date "2006-01-01" @default.
- W1974396710 modified "2023-09-23" @default.
- W1974396710 title "Insights into the making of a stable silylene" @default.
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- W1974396710 doi "https://doi.org/10.1039/b514666f" @default.
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