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• W1974433644 abstract "Reversible addition-fragmentation chain transfer (RAFT) equilibrium constants, K(eq), for the model system cyano-iso-propyl dithiobenzoate (CPDB) - cyano-iso-propyl radical (CIP) have been deduced via electron paramagnetic resonance (EPR) spectroscopy. The CIP species is produced by thermal decomposition of azobis-iso-butyronitrile (AIBN). In solution of toluene at 70 °C, K(eq) has been determined to be (9 ± 1) L · mol(-1). Measurement of K(eq) = k(ad)/k(β) between 60 and 100 °C yields ΔE(a) = (-28 ± 4) kJ · mol(-1) as the difference in the activation energies of k(ad) and k(β). The data measured on the model system are indicative of fast fragmentation of the intermediate radical produced by addition of CIP to CPDB." @default.
• W1974433644 created "2016-06-24" @default.
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• W1974433644 creator A5055116080 @default.
• W1974433644 date "2011-07-07" @default.
• W1974433644 modified "2023-10-16" @default.
• W1974433644 title "Assessing the RAFT Equilibrium Constant via Model Systems: An EPR Study" @default.
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• W1974433644 doi "https://doi.org/10.1002/marc.201100228" @default.
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