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• W1974434510 abstract "Surface-enhanced Raman spectroscopy has been used to study the molecular interactions of malononitrile with copper electrode surfaces. The doubly degenerate CN stretching frequency at 2263 cm−1 is removed when malononitrile adsorbs on copper. Two ν(CN) bands are observed at 2096 and 2204 cm−1 at −0.6 V(SCE). The result shows that only one CN group is π-coordinated with Cu, which contributes to the observed large shift (−167 cm−1) in ν(CN). The other CN group is not coordinated to the metal surface." @default.
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• W1974434510 date "1985-09-01" @default.
• W1974434510 modified "2023-10-16" @default.
• W1974434510 title "Enhanced Raman spectroscopic study of the coordination chemistry of malononitrile on copper surfaces: Removal of ν(CN) degeneracy through π-coordination" @default.
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• W1974434510 doi "https://doi.org/10.1016/0009-2614(85)80423-1" @default.
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