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• W1974435265 abstract "The non-ionic surfactant Brij 35 was effectively removed from concentrated aqueous solution by the peroxymonosulfate/Co(II) system, using oxone (2KHSO(5)·KHSO(4)·K(2)SO(4)) as a source of peroxymonosulfate. At pH=2.3 and initial Brij 35 concentration in the range 680-2410 mg L(-1), 86-94% removal was achieved after 24 h, using Co(II)=15 μM and oxone=5.9 mM. The effectiveness of removal did not change when initial pH was in the range 2.3-8.2. After five subsequent additions of Co(II) and oxone to the solution, COD and TOC removals increased up to 64% and 33%, respectively. Radical quenching tests confirmed that sulfate radical was the dominant radical species in the system. The main identified by-products from surfactant degradation were: (a) low molecular weight organic acids; (b) aldehydes and formates with shorter ethoxy chain than Brij 35; (c) alcohol ethoxylates carrying hydroxyl groups bonded to ethoxy chain. By-products identification allowed to hypothesize the pathways of Brij 35 degradation." @default.
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• W1974435265 date "2012-01-01" @default.
• W1974435265 modified "2023-10-18" @default.
• W1974435265 title "Peroxymonosulfate–Co(II) oxidation system for the removal of the non-ionic surfactant Brij 35 from aqueous solution" @default.
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• W1974435265 doi "https://doi.org/10.1016/j.chemosphere.2011.09.010" @default.
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