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- W1974436411 abstract "Mixtures of pure elemental Al and Nb powders of Nb–75 at-%Al and Nb–25 at-%Al composition were mechanically alloyed. Phase transformation of the powder mixtures was investigated by X-ray diffraction technique. It was found that mechanical alloying of the Nb–75 at-%Al powder mixture led to the formation of Nb(Al) solid solution and subsequent formation of DO22-NbAl3 intermetallic compound, and no amorphous phase was formed after longer milling times. The results showed that mechanical alloying of Nb–25 at-%Al for 8 h led to the formation of amorphous phase, and Nb3Al intermetallic was not formed during milling. A thermodynamic analysis was carried out based on the semiempirical theory of Miedema. This analysis showed that there is a driving force for the Nb–Al binary to form a solid solution for all compositions while the amorphous phase is stable in the range of 0·1⩽xAl⩽0·95." @default.
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- W1974436411 date "2012-04-01" @default.
- W1974436411 modified "2023-10-03" @default.
- W1974436411 title "Thermodynamic analysis of nanocrystalline and amorphous phase formation in Nb–Al system during mechanical alloying" @default.
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- W1974436411 doi "https://doi.org/10.1179/1743290111y.0000000018" @default.
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