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- W1974459247 abstract "Catalytic enantioselective direct vinylogous Michael addition of α,α-dicyanoalkenes to 2-enoylpyridine N-oxides with a bifunctional organocatalyst is described. The methodology offers an efficient way to install an asymmetric carbon–carbon bond at the γ-position of α,α-dicyanoalkenes in excellent regio-, diastereo-, and enantioselectivity. Further, application in desymmetrization of achiral α,α-dicyanoalkene to access highly functionalized enantioenriched cyclohexylidenemalononitrile derivatives has been demonstrated." @default.
- W1974459247 created "2016-06-24" @default.
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- W1974459247 date "2014-10-13" @default.
- W1974459247 modified "2023-10-07" @default.
- W1974459247 title "Asymmetric Direct Vinylogous Michael Addition to 2-Enoylpyridine <i>N</i>-Oxides Catalyzed by Bifunctional Thio-Urea" @default.
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- W1974459247 doi "https://doi.org/10.1021/ol5025794" @default.
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