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• W1974472539 abstract "Group 4 metallocenes and ansa-metallocenes are known for their role in the Ziegler-Natta catalysis of olefins and in the catalytic dehydrocoupling of hydrosilanes to form polysilanes. This report describes the crystal structures of three carbon-bridged ansa-metallocene dichlorides, Me2C((C5H4)2)MCl2 (M = Ti (1), Zr (2) and Hf (3)). Comparisons of the structures of the molecules with previously characterized systems is made; in particular, the Cpcentroid-M-Cpcentroid angle, the position of the metal relative to the cyclopentadienyl rings and the uniformity of the CC bond lengths in the Cp rings are discussed. Comparisons between structure and reactivity in the dehydrocoupling of hydrosilanes are described." @default.
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• W1974472539 date "1995-11-01" @default.
• W1974472539 modified "2023-09-23" @default.
• W1974472539 title "The X-ray crystal structures of the ansa-metallocenes, Me2C(C5H4)2MCl2 (M = Ti, Zr and Hf)" @default.
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• W1974472539 doi "https://doi.org/10.1016/0022-328x(95)05561-3" @default.
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