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- W1974481299 abstract "Ein neues Verfahren zur Synthese der Titel-Verbindungen uber cis-Bis(4-bromphenyl)-bis(tributylphosphan)platin(II) (cis-2a) und cis-Bis(4-lithiophenyl)bis(tributylphosphan)-platin(II) (cis-3) wird beschrieben. Mit dieser Methode wurden die Verbindungen cis-{Pt[P(n-Bu)3]2[C6H4X- (4)]2} (X D, Si(CH3)3, CO2H, CO2CH3, CN, COC6H5) (cis-2b–g) und trans-{Pt[P(n-Bu)3]2[C6H4I- (4)]2} (trans-2h) synthetisiert; aus cis-2a–c, e–g wurden unter Katalyse mit Tetrabutylammoniumiodid die zugehorigen trans-Isomeren trans-2a–c, e–g erhalten.Syntheses of cis- and trans-Bis(X-phenyl)bis(tributylphosphane)platinum(II) Compounds with Substituents of π-Acceptor Character in the Platinum-Bound Phenyl RingsA new synthetic route to the title compounds via cis-bis(4-bromophenyl)bis(tributylphos-phane)platinum(II) (cis-2a) and cis-bis(4-lithiophenyl)bis(tributylphosphane)platinum(II) (cis-3) is described. By this method the compounds cis-{Pt[P(nBu)3]2[C6H4X-(4)]2} (X D, Si(CH3)3, CO2H, CO2CH3, CN, COC6H5) (cis-2b–g) and trans-{Pt[P(nBu)3]2[C6H4I-(4)]2} (trans-2h) have been synthesized; cis-2a–c, e–g have been transformed into their trans- isomers trans-2a–c, e–g by catalysis with tetrabutylammonium iodide." @default.
- W1974481299 created "2016-06-24" @default.
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- W1974481299 date "1985-11-01" @default.
- W1974481299 modified "2023-09-24" @default.
- W1974481299 title "Synthesen voncis- undtrans-Bis(X-phenyl)- bis(tributylphosphan)platin(II)-Verbindungen mit Substituenten von π-Akzeptor-Charakter in den platingebundenen Phenyl-Ringen" @default.
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- W1974481299 doi "https://doi.org/10.1002/cber.19851181107" @default.
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