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• W1974486395 abstract "The effects of cation symmetry and packing on the mixed-valence state of binuclear ferrocene derivatives are discussed separately by using chiral isomers and racemic modification of 1‘,1‘ ‘‘-bis(2-phenylbutyl)-1,1‘ ‘-biferrocenium pentaiodide. The pentaiodide anion has a polymeric structure and is composed of triiodide anion and iodine molecule units. The (R,S) isomer having an inversion center shows a detrapped-valence state even at 78 K. On the other hand, the (R,R) and the (S,S) isomers having no inversion center show a trapped-valence state at room temperature. The racemic modification, however, consisting of the (R,R) and the (S,S) isomers shows a perfect detrapped-valence state at room temperature. This finding shows that the packing effect overcomes the effect of cation asymmetry." @default.
• W1974486395 created "2016-06-24" @default.
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• W1974486395 date "2003-07-26" @default.
• W1974486395 modified "2023-09-23" @default.
• W1974486395 title "Mixed-Valence State of Optically Active 1‘,1‘ ‘‘-Bis(2-phenylbutyl)-1,1‘ ‘-biferrocenium Pentaiodide: Effects of Cation Symmetry and Intermolecular Interaction on Trapped-/Detrapped-Valence States" @default.
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• W1974486395 doi "https://doi.org/10.1021/ic0343455" @default.
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