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- W1974525675 abstract "Starting from simple amino acid esters and Merrifield resins, a small library of polymer-bound chiral-β-amino alcohols can be prepared. By reaction with LiALH4 the corresponding chiral reducing agents are obtained, having structural variations at both the α and β positions. All supported reagents are able to reduce acetophenone to 1-phenylethanol. Enantioselectivity is observed when the steric hindrance in the chiral fragment is increased. Best results are obtained for the supported derivative of α,α-diphenyl phenylalaninol." @default.
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- W1974525675 date "1999-09-01" @default.
- W1974525675 modified "2023-10-18" @default.
- W1974525675 title "Small Libraries of Polymer-Supported Amino Alcohols: An Application to the Enantioselective Reduction of Acetophenone by LAH" @default.
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- W1974525675 doi "https://doi.org/10.1002/(sici)1099-0690(199909)1999:9<2263::aid-ejoc2263>3.0.co;2-2" @default.
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