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• W1974558600 abstract "Anthracene, biphenyl and selected mixtures have been carbonised to a maximum temp, of 600°C, under pressures approaching 300 MNm−2(3 kbar) whilst sealed in gold tubes and contained within a hydrothermal pressure bomb. Resultant carbons were analysed by Stereoscan microscopy, mass spectrometry, X-ray diffraction techniques and optical microscopy. The carbons were graphitised at 2000† and 2800†C and examined. A new phenomenon was observed, namely the formation of a spherulitic (botryoidal) carbon, about μ-sized, which although intrinsically anisotropic can confer isotropic properties to the bulk graphite. These spheres are essentially the mesophase, the effect of pressure being to prevent their coalescence. Pressure enhances the graphitisibility of the carbons. The addition of biphenyl reduces the graphitisibility of the carbonised anthracene, but a mechanism involving co-condensation of biphenyl and anthracene molecules is not considered to be invoked, rather a dilution of the anthracene, thus preventing mesophase growth." @default.
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• W1974558600 date "1971-03-01" @default.
• W1974558600 modified "2023-10-18" @default.
• W1974558600 title "The carbonisation of anthracene and biphenyl under pressures of 300 MNm (3 kbar)" @default.
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• W1974558600 doi "https://doi.org/10.1016/0008-6223(71)90128-x" @default.
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