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- W1974584013 abstract "Triple-decker complexes with a bridging diborolyl ligand CpCo(μ-1,3-C3B2Me5)M(CO)3 (M = Mn, 2; Re, 3), CpCo(μ-1,3-C3B2Me5)Ru(CO)2Cl (4) and CpCo(μ-1,3-C3B2Me5)Ru(CO)(μ-CO)2Ru(CO)Cp (5) were synthesized by reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]– (1) with [(naphthalene)Mn(CO)3]+, [Re(CO)3(THF)2Br]2, or [Ru(CO)3Cl2]2. Structures of 4 and 5 were determined by X-ray diffraction. The spectroelectrochemical behaviour of compounds 2 and 3 was studied. IR-spectroscopical and computational data suggest that anion 1 is significantly stronger donor than Cp− but slightly weaker than Cp*–." @default.
- W1974584013 created "2016-06-24" @default.
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- W1974584013 date "2014-09-01" @default.
- W1974584013 modified "2023-10-18" @default.
- W1974584013 title "μ-Diborolyl triple-decker complexes with carbonyl ligands: Synthesis, structures and electrochemistry" @default.
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- W1974584013 doi "https://doi.org/10.1016/j.jorganchem.2014.06.001" @default.
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