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- W1974621363 abstract "A photoluminescent multilayer film based on Keggin-type polyoxometalate PMo12O403− (PMo12) and transition metal complex tris(2,2-bipyridine) ruthenium [Ru(bpy)3]2+ (Ru(bpy)) was prepared by using layer-by-layer assembly(LBL). The formation of multilayer film was monitored by ultraviolet absorption spectra. The absorption intensity of characteristic peaks increase with a four-layer cycle, indicating that the LBL assembly film grow linearly and reproducibly from layer to layer. The composition of the film was measured by X-ray photoelectron spectrum (XPS). The data of XPS confirmed the presence of the expected elements. The film exhibited photoluminescence arising from π*−t2g ligand-to-metal transition of Ru(bpy) and redox activity attributing to molybdenum-centered redox processes of PMo12. The surface morphology of multilayer film was characterized by atomic force microscopy (AFM). The result shows that the film had a smooth surface with root-mean-square (rms) roughness ca. 1.363 nm for {PEI/(PSS/PEI/PMo12/Ru(bpy))3}. The grains are homogeneously dispersed in the substrate and have a rather narrow diameter size distribution." @default.
- W1974621363 created "2016-06-24" @default.
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- W1974621363 date "2004-10-01" @default.
- W1974621363 modified "2023-10-17" @default.
- W1974621363 title "Photoluminescent multilayer film based on polyoxometalate and tris(2,2-bipyridine)ruthenium" @default.
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- W1974621363 doi "https://doi.org/10.1016/j.jssc.2004.05.054" @default.
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