FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1974642528> ?p ?o ?g. }

• W1974642528 endingPage "1944" @default.
• W1974642528 startingPage "1937" @default.
• W1974642528 abstract "Schiff-base lateral macrobicycles containing two different binding units, a rigid and unsaturated N(2)X set (X: N, O) and a flexible and cyclic N(2)O(n)() set, linked by two aromatic bridges, have been prepared by reaction of the appropriate bibracchial diamines N,N'-bis(aminobenzyl)-diaza-crown and diformyl precursors in the presence of Ba(II) as templating agent. The expected cryptands do not form in the absence of the cation; the presence of this metal ion is necessary to orient the diamine precursor in a syn conformation. Comparison of the X-ray crystal structures of the barium complex of the bibracchial diamine N,N'-bis(2-aminobenzyl)-1,10-diaza-15-crown-5 and the barium complex of the cryptand derived from it incorporating a pyridine unit indicates that the encapsulation of the metal ion is clearly more effective in the case of the cryptand. The coordination of Ba(II) ion to the pyridine nitrogen atom promotes the displacement of the metal into the cavity of the cryptand as well as important changes in the conformation of the crown unit, although the fold of the pendant arms remains practically unchanged. The cryptands reported constitute the first example of a novel family of macrobicycles." @default.
• W1974642528 created "2016-06-24" @default.
• W1974642528 creator A5029701197 @default.
• W1974642528 creator A5033539854 @default.
• W1974642528 creator A5037308279 @default.
• W1974642528 creator A5051385433 @default.
• W1974642528 creator A5064919263 @default.
• W1974642528 creator A5072958886 @default.
• W1974642528 creator A5073252198 @default.
• W1974642528 creator A5075027886 @default.
• W1974642528 creator A5086295644 @default.
• W1974642528 creator A5090491171 @default.
• W1974642528 date "1999-04-01" @default.
• W1974642528 modified "2023-10-17" @default.
• W1974642528 title "Barium Templating Schiff-Base Lateral Macrobicycles" @default.
• W1974642528 cites W1171346759 @default.
• W1974642528 cites W1964040559 @default.
• W1974642528 cites W1970473422 @default.
• W1974642528 cites W1971477649 @default.
• W1974642528 cites W1973221387 @default.
• W1974642528 cites W1988214547 @default.
• W1974642528 cites W1993395069 @default.
• W1974642528 cites W1998722626 @default.
• W1974642528 cites W2002750581 @default.
• W1974642528 cites W2006687227 @default.
• W1974642528 cites W2009437561 @default.
• W1974642528 cites W2016857507 @default.
• W1974642528 cites W2093282918 @default.
• W1974642528 cites W2105767327 @default.
• W1974642528 cites W2325664793 @default.
• W1974642528 cites W2064089996 @default.
• W1974642528 doi "https://doi.org/10.1021/ic9811190" @default.
• W1974642528 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11670968" @default.
• W1974642528 hasPublicationYear "1999" @default.
• W1974642528 type Work @default.
• W1974642528 sameAs 1974642528 @default.
• W1974642528 citedByCount "34" @default.
• W1974642528 countsByYear W19746425282012 @default.
• W1974642528 countsByYear W19746425282014 @default.
• W1974642528 countsByYear W19746425282017 @default.
• W1974642528 countsByYear W19746425282019 @default.
• W1974642528 countsByYear W19746425282022 @default.
• W1974642528 crossrefType "journal-article" @default.
• W1974642528 hasAuthorship W1974642528A5029701197 @default.
• W1974642528 hasAuthorship W1974642528A5033539854 @default.
• W1974642528 hasAuthorship W1974642528A5037308279 @default.
• W1974642528 hasAuthorship W1974642528A5051385433 @default.
• W1974642528 hasAuthorship W1974642528A5064919263 @default.
• W1974642528 hasAuthorship W1974642528A5072958886 @default.
• W1974642528 hasAuthorship W1974642528A5073252198 @default.
• W1974642528 hasAuthorship W1974642528A5075027886 @default.
• W1974642528 hasAuthorship W1974642528A5086295644 @default.
• W1974642528 hasAuthorship W1974642528A5090491171 @default.
• W1974642528 hasConcept C114595235 @default.
• W1974642528 hasConcept C115624301 @default.
• W1974642528 hasConcept C145148216 @default.
• W1974642528 hasConcept C155647269 @default.
• W1974642528 hasConcept C178790620 @default.
• W1974642528 hasConcept C179104552 @default.
• W1974642528 hasConcept C185592680 @default.
• W1974642528 hasConcept C188027245 @default.
• W1974642528 hasConcept C2776428424 @default.
• W1974642528 hasConcept C2779485729 @default.
• W1974642528 hasConcept C2780871995 @default.
• W1974642528 hasConcept C542576722 @default.
• W1974642528 hasConcept C544153396 @default.
• W1974642528 hasConcept C71240020 @default.
• W1974642528 hasConcept C8010536 @default.
• W1974642528 hasConceptScore W1974642528C114595235 @default.
• W1974642528 hasConceptScore W1974642528C115624301 @default.
• W1974642528 hasConceptScore W1974642528C145148216 @default.
• W1974642528 hasConceptScore W1974642528C155647269 @default.
• W1974642528 hasConceptScore W1974642528C178790620 @default.
• W1974642528 hasConceptScore W1974642528C179104552 @default.
• W1974642528 hasConceptScore W1974642528C185592680 @default.
• W1974642528 hasConceptScore W1974642528C188027245 @default.
• W1974642528 hasConceptScore W1974642528C2776428424 @default.
• W1974642528 hasConceptScore W1974642528C2779485729 @default.
• W1974642528 hasConceptScore W1974642528C2780871995 @default.
• W1974642528 hasConceptScore W1974642528C542576722 @default.
• W1974642528 hasConceptScore W1974642528C544153396 @default.
• W1974642528 hasConceptScore W1974642528C71240020 @default.
• W1974642528 hasConceptScore W1974642528C8010536 @default.
• W1974642528 hasIssue "8" @default.
• W1974642528 hasLocation W19746425281 @default.
• W1974642528 hasLocation W19746425282 @default.
• W1974642528 hasOpenAccess W1974642528 @default.
• W1974642528 hasPrimaryLocation W19746425281 @default.
• W1974642528 hasRelatedWork W1110102617 @default.
• W1974642528 hasRelatedWork W1993984365 @default.
• W1974642528 hasRelatedWork W2025108913 @default.
• W1974642528 hasRelatedWork W2026994116 @default.
• W1974642528 hasRelatedWork W2148465657 @default.
• W1974642528 hasRelatedWork W2378463076 @default.
• W1974642528 hasRelatedWork W3082025483 @default.
• W1974642528 hasRelatedWork W3184797523 @default.
• W1974642528 hasRelatedWork W4308922063 @default.
• W1974642528 hasRelatedWork W4328054792 @default.

• next