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• W1974661898 endingPage "1329" @default.
• W1974661898 startingPage "1316" @default.
• W1974661898 abstract "We present a new class of phosphorescent cyclometalated iridium(III) bipyridyl–phenylenediamine complexes [Ir(N^C)2(bpy-DA)](PF6) (bpy-DA=4-(N-(2-amino-5-methoxyphenyl)aminomethyl)-4′-methyl-2,2′-bipyridine; HN^C=2-(2,4-difluorophenyl)pyridine (Hdfppy) (1 a), 2-phenylpyridine (Hppy) (2 a), 2-phenylquinoline (Hpq) (3 a), 2-phenylcinchoninic acid methyl ester (Hpqe) (4 a)) and their triazole counterparts [Ir(N^C)2(bpy-T)](PF6) (bpy-T=4-((6-methoxybenzotriazol-1-yl)methyl)-4′-methyl-2,2′-bipyridine; HN^C=Hdfppy (1 b), Hppy (2 b), Hpq (3 b), Hpqe (4 b)). Upon photoexcitation, the diamine complexes exhibited fairly weak green to red phosphorescence under ambient conditions whereas the triazole derivatives emitted strongly. The photophysical properties of complexes 2 a and 2 b have been studied in more detail. Upon protonation, the diamine complex 2 a displayed increased emission intensity, but the emission properties of its triazole counterpart complex 2 b were independent on the pH value of the solution. Also, complex 2 a was found to be readily converted into complex 2 b upon reaction with NO under aerated conditions, resulting in substantial emission enhancement of the solution. The reaction was highly specific toward NO over other reactive oxygen and nitrogen species (RONS) as revealed by spectroscopic analyses. The lipophilicity and cellular uptake efficiency of the diamine complexes have been examined and correlated to their molecular structures. Also, cell-based assays showed that these complexes were noncytotoxic toward human cervix epithelioid carcinoma (HeLa) cells (at 10 μM, 4 h, percentage survival ≈80–95 %). Additionally, the diamine complexes have been used to visualize intracellular NO generated both exogenously in HeLa cells and endogenously in RAW 264.7 murine macrophages by laser-scanning confocal microscopy." @default.
• W1974661898 created "2016-06-24" @default.
• W1974661898 creator A5003471606 @default.
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• W1974661898 creator A5072072184 @default.
• W1974661898 creator A5081167307 @default.
• W1974661898 creator A5088817458 @default.
• W1974661898 date "2014-03-18" @default.
• W1974661898 modified "2023-10-10" @default.
• W1974661898 title "Cyclometalated Iridium(III) Bipyridyl-Phenylenediamine Complexes with Multicolor Phosphorescence: Synthesis, Electrochemistry, Photophysics, and Intracellular Nitric Oxide Sensing" @default.
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