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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1974696912> ?p ?o ?g. }

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• W1974696912 abstract "The transmission of substituent effects across the palladium center to the allyl carbons is monitored by 13C NMR and X-ray crystallography as a way to probe electronic asymmetry in chiral ligand design. Based on their similar chemical shift trends and X-ray structures, the π-allylpalladium intermediates provide a good model for early transition state reactions, which are less sensitive to electronic perturbations. Hammett analysis supports an electronic basis for enantioselection that increases as the transition state becomes later." @default.
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• W1974696912 date "2005-02-01" @default.
• W1974696912 modified "2023-09-23" @default.
• W1974696912 title "Hammett 13C NMR and X-ray studies of π-allylpalladium phosphinooxazoline chiral ligand complexes" @default.
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• W1974696912 doi "https://doi.org/10.1016/j.tetlet.2005.01.032" @default.
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