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• W1974697112 abstract "High-index surfaces of a face-centered cubic metal (e.g., Pd, Pt) have a high density of low-coordinated surface atoms and therefore possess enhanced catalysis activity in comparison with low-index faces. However, because of their high surface energy, the challenge of chemically preparing metal nanocrystals having high-index facets remains. We demonstrate in this work that introducing amines as the surface controller allows concave Pt nanocrystals having {411} high-index facets to be prepared through a facile wet-chemical route. The as-prepared Pt nanocrystals display a unique octapod morphology with {411} facets. The presence of high-index {411} exposed facets endows the concave Pt nanocrystals with excellent electrocatalytic activity in the oxidation of both formic acid and ethanol." @default.
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• W1974697112 date "2011-03-15" @default.
• W1974697112 modified "2023-09-30" @default.
• W1974697112 title "Amine-Assisted Synthesis of Concave Polyhedral Platinum Nanocrystals Having {411} High-Index Facets" @default.
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• W1974697112 doi "https://doi.org/10.1021/ja1117528" @default.
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