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- W1974709466 abstract "Abstract The structure of Na-doped YBa 2 Cu 3 O 7−δ superconductors has been studied at room temperature with the neutron-powder-diffraction method and profile analysis. The compound is found to be orthorhombic with space group Pmmm. Na + ions randomly substitute for about 9% of the Y 3+ ions at the Y site ( 1 2 , 1 2 , 1 2 ). The substitution reduces the charge at the Y sites and results in a shifting of oxygen in the Cu(2) layer away from the Y site as well as barium towards the Y site. Good agreement in the fit is obtained by assuming that oxygen in the Cu(1) layer fully or almost fully occupies the O(4) site and partially occupies the O(5) site. Moreover, the O(4) sites are possibly disordered by about 0.2 A away from the ideal positions towards barium." @default.
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- W1974709466 date "1995-06-01" @default.
- W1974709466 modified "2023-09-27" @default.
- W1974709466 title "Neutron powder diffraction study of the crystal structure of Na-doped Y-1-2-3 high-Tc superconductor" @default.
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- W1974709466 doi "https://doi.org/10.1016/0921-4534(95)00228-6" @default.
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