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• W1974779897 abstract "In synthetic chlorite-like complexes, amounts of amorphous and/or crystalline hydrous aluminum oxide were determined through use of H-bentonite that converts into Albentonite by reaction with Al-gel or gibbsite. In Al(OH) x -complexes with less than 1,000 mequiv. of Al per 100 g of clay, hydrous aluminum oxide gel remains held on clay surfaces without crystallizing for a long time. The neutralization reaction between a one-symmetry-concentration of H-bentonite and chlorite-like complexes at 10°C is initially very fast and seems to affect exclusively the hydrous oxide in suspension or adsorbed on the external surfaces and edges of clay particles. After a few hours, the interlayer Al-gel begins to be neutralized and the reaction rate decreases according to first-order kinetics. In complexes of equal ages, more time is required to neutralize the hydrous oxide precipitated in the presence of clay than added to the clay, because of a different interlayering. The kinetics of reactions between complexes characterized by amorphous and crystalline aluminum hydroxide (more than 1,000 mequiv. aluminum per 100 g of clay) and H-bentonites were studied. H-bentonite reacts with gibbsite much more slowly than it does with amorphous forms, always according to first order kinetics." @default.
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• W1974779897 date "1978-10-01" @default.
• W1974779897 modified "2023-09-25" @default.
• W1974779897 title "Interactions between H-bentonite and aluminous chlorite-like complexes" @default.
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• W1974779897 doi "https://doi.org/10.1016/0016-7061(78)90023-x" @default.
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