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- W1974862516 abstract "Adsorption of ethanol 2-propanol, and tert-butanol has been studied on a well-characterized anatase sample using volumetric and ir techniques. Differences in the adsorption capacities for the three alcohols have been interpreted as due to the same electronic and steric effects that determine changes in the maximum coordination for the TiIV ions in titanium alkoxides. Decomposition of the adsorbed phase was followed by ir and TPD (temperature-programmed decomposition) methods and was compared with the catalytic dehydration of the respective alcohols. The agreement between the kinetic parameters for both processes indicates that the slowest step for the catalytic reaction corresponds to a monomolecular decomposition of the adsorbed species, as supported by studies of water displacement from the anatase surface by all three alcohols." @default.
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- W1974862516 date "1977-08-01" @default.
- W1974862516 modified "2023-10-16" @default.
- W1974862516 title "Study of the interaction of aliphatic alcohols with TiO2 I. Decomposition of ethanol, 2-propanol, and tert-butanol on anatase" @default.
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- W1974862516 doi "https://doi.org/10.1016/0021-9517(77)90253-6" @default.
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