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- W1974865003 abstract "Cooled porous metal burners are shown to have great advantages for the study of chemical kinetics in flames and flame gases. A method is described for determining quantitatively the concentration of the OH radical in flame gases and measurements are reported for rich hydrogen-air flames. The OH concentrations near the flame are shown to be always in considerable excess of the calculated equilibrium concentrations. These excess concentrations decay in a manner which can be explained by assuming that the reaction OH+H2⇌H2O+H is fast in both directions so that the OHH ratio is always the equilibrium ratio. Both radicals then decay by the three body recombinations of H with itself and with OH to form H2 and H2O. It is shown that for the slower flames the diffusion of the radicals can lead to erroneous results." @default.
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- W1974865003 date "1958-09-01" @default.
- W1974865003 modified "2023-09-23" @default.
- W1974865003 title "Hydroxyl concentrations in rich hydrogen-air flames held on porous burners" @default.
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- W1974865003 doi "https://doi.org/10.1016/0010-2180(58)90044-0" @default.
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