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• W1974868608 startingPage "8082" @default.
• W1974868608 abstract "Asymmetric syntheses of two of GlaxoSmithKline’s highly potent phosphodiesterase IV inhibitors CMPI 1 and CMPO 2 have been accomplished from nitroethane and simple precursors in 8 and 7 steps, respectively. The suggested synthetic strategy involves as a key stage the silylation of enantiopure six-membered cyclic nitronates. In vitro studies of PDE IVB1 inhibition revealed a significant difference in the activity of CMPI 1 and CMPO 2 enantiomers." @default.
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• W1974868608 date "2013-01-01" @default.
• W1974868608 modified "2023-10-01" @default.
• W1974868608 title "Synthesis of PDE IV inhibitors. First asymmetric synthesis of two of GlaxoSmithKline's highly potent Rolipram analogues" @default.
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• W1974868608 doi "https://doi.org/10.1039/c3ob41646a" @default.
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