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- W1974881948 abstract "The reaction entropy, ΔSor, for the electroreduction of p-dicyanobenzene, anthracene and nitromesitylene has been measured in a number of solvents using a non-isothermal cell. The solvent effect on the values of ΔSor has been discussed in terms of the Born dielectric continuum model and the specific solvation given by the solvent parameters of Lewis acidity and basicity. A correlation between the solvent acceptor number and ΔSor values is observed in the case of p-dicyanobenzene radical anions with a localized charge at the cyano groups, whereas the dielectric approach is more important for anthracene radicals with a stronger charge delocalization when the specific solvation is much weaker. A two-parameter correlation with acceptor and donor numbers has been observed for the ΔSor values of nitromesitylene where association between the radical anions and electrolyte cations occurs. An increase in the ΔSor values for the reduction of o-naphthoquinone in dimethylsulphoxide with an increase in the association constant for a series of cations has been found." @default.
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- W1974881948 date "1987-03-01" @default.
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- W1974881948 title "Solvent and ion pairing effects on the reaction entropy for the electroreduction of aromatic molecules" @default.
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- W1974881948 doi "https://doi.org/10.1016/0022-0728(87)85041-6" @default.
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