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- W1974906918 abstract "A carbon-coated nanocrystalline LiFePO4 cathode material was synthesized by pyrolysis of polyacrylate precursor containing Li+, Fe3+ and PO4−. The powder X-ray diffraction (XRD) and high-resolution TEM micrographs revealed that the LiFePO4/C composite as prepared has a core-shell structure with pure olivine LiFePO4 crystallites as cores and intimate carbon coating as a shell layer. Between the composite particulates, there exists a carbon matrix binding the nanocrystallites together into micrometer particles. The electrochemical measurements demonstrated that the LiFePO4/C composite with an appropriate carbon content can deliver a very high discharge capacity of 157 mAh g−1 (>92% of the theoretical capacity of LiFePO4) with 95% of its initial capacity after 30 cycles. Since this preparation method uses less costly materials and operates in mild synthetic conditions, it may provide a feasible way for industrial production of the LiFePO4/C cathode materials for the lithium-ion batteries." @default.
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- W1974906918 date "2007-10-01" @default.
- W1974906918 modified "2023-09-24" @default.
- W1974906918 title "Synthesis and electrochemical characterization of carbon-coated nanocrystalline LiFePO4 prepared by polyacrylates-pyrolysis route" @default.
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- W1974906918 doi "https://doi.org/10.1016/j.jpowsour.2007.05.013" @default.
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