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- W1974930289 abstract "The adsorption isotherms of four commonly used quaternary ammonium pairing ions in aqueous solution on ODS Hypersil are reported. The capacity factors of four substituted benzoic acids as test solutes are measured as a function of pairing ion concentration under conditions of complete solute ionisation. The chromatographic behaviour of an undissociated solute, 5-hydroxymethylfurfuraldehyde, is also examined under these conditions. Over the wide range of pairing-ion concentrations used, maximum values of capacity factors are observed. A mechanism of retention, combining desolvation and ion exchange, which considers the effect of adsorbed pairing ion on surface available for desolvation is proposed. On the basis of this mechanism an equation relating capacity factor and adsorbed pairing-ion concentration is derived. The data obtained in this investigation are fitted to the equation and the desolvation and ion-exchange constants are estimated. The behaviour of the neutral solute 5-hydroxymethylfurfuraldehyde is examined in the light of the derived equation." @default.
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- W1974930289 date "1980-12-01" @default.
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- W1974930289 title "Mechanism of retention of acidic solutes by octadecyl silica using quaternary ammonium pairing ions as ion exchangers" @default.
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- W1974930289 doi "https://doi.org/10.1016/s0021-9673(00)91817-x" @default.
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