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- W1974969543 abstract "Alkynyl carboxylic acids reacted with aryl iodides under a CO atmosphere in the presence of a palladium catalyst to produce α,β-alkynyl aryl ketones in good yields. The maximum turnover number was 16 800. The desired carbonylative coupling was formed from phenyl propiolic acid without any formation of a noncarbonylative coupling product in the absence of CuI. However, the reaction with alkyl-substituted alkynyl carboxylic acids required CuI as a cocatalyst for high yield." @default.
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- W1974969543 date "2011-01-28" @default.
- W1974969543 modified "2023-10-08" @default.
- W1974969543 title "Pd-Catalyzed Carbonylative Reactions of Aryl Iodides and Alkynyl Carboxylic Acids via Decarboxylative Couplings" @default.
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- W1974969543 doi "https://doi.org/10.1021/ol102993y" @default.
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