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- W1974996945 abstract "The behaviour towards RhI of a new ligand containing three linked pyrazoles (HLL) has been studied. Depending on which diolefin, COD or TFB, is used, mono or dinuclear complexes are obtained. The structures of the four complexes, [RHCl(COD)(HLL)], [{RhCl(TFB]}2(μ-HLL)], [Rh(LL)(COD)] and [{Rh(TFB)}2(μ-LL)BF4, have been established by 1H and 13C NMR spectroscopy. In most cases, the NMR spectra reveal fluxional processes involving not only the RhI metal but also the N-H proton and the diolefin." @default.
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- W1974996945 date "1991-07-01" @default.
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- W1974996945 title "Rhodium(I) complexes with the polydentate ligand 3,5-bis(4-methylpyrazol-1-yl)-4-methylpyrazole" @default.
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- W1974996945 doi "https://doi.org/10.1016/0022-328x(91)86061-t" @default.
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