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- W1975083471 abstract "Spectral studies of the neodymium complexes of formula [Nd(TMU) 6 ](ClO 4 ) 3 , [Nd(CF 3 SO 3 )(TMU) 5 ](CF 3 SO 3 ) 2 , [Nd(NCS) 3 (TMU) 4 ], [Nd(NO 3 ) 3 (TMU) 3 ], [NdCl 3 (TMU) 3 ] and [Nd(TMU) 3 (H 2 O) 6 ]Br 3 were made. The spectra of the compounds were recorded in the regions of 4 G 5 2 , 2 G 7 2 ← 4 I 9 2 (I) and 2 P 1 2 ← 4 I 9 2 (H) transitions in the solid state, at room temperature and at 77 K and also in acetonitrile solutions. For the cubic perchlorate and hexafluorophosphate complexes the crystal-field parameters ( B k q ) were calculated by the equivalent operator method. The nephelauxetic ( ̄ gb), covalent ( b 1 2 ) and Sinha (δ) parameters were determined for all the compounds. The oscillator strengths, in acetonitrile, for the hypersensitive (I) bands were also calculated and related to the basicity of the anions." @default.
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- W1975083471 date "1989-04-01" @default.
- W1975083471 modified "2023-09-27" @default.
- W1975083471 title "Spectral studies of neodymium complexes containing tetramethylurea (TMU) as ligand" @default.
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- W1975083471 doi "https://doi.org/10.1016/0022-5088(89)90039-8" @default.
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