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- W1975111202 abstract "The carboxylate oxygen of thimerosal, [(ArCO2)SHgEt]Na, is subject to facile electrophilic attack by H+ and [HgEt]+ to give (ArCO2H)SHgEt and [(ArCO2HgEt)SHgEt]2, respectively. X-Ray diffraction demonstrates that (ArCO2H)SHgEt exists as a hydrogen bonded dimer in the solid state whereas [(ArCO2HgEt)SHgEt]2 is tetranuclear, with the mercury centers being connected by bridging carboxylate groups. 1H NMR spectroscopic studies indicate that the form of the 199Hg satellites of the ethyl group of (ArCO2H)SHgEt are dependent on the magnetic field, such that the inner pair of CH2 and CH3 satellites appear as a singlet at 400 MHz, as a consequence of 2JHg–H and 3JHg–H having opposite signs and the difference in chemical shifts of the central CH2 and CH3groups being equal to ½{|2JHg–H−3JHg–H|}." @default.
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- W1975111202 date "2009-01-01" @default.
- W1975111202 modified "2023-09-26" @default.
- W1975111202 title "Molecular structures of protonated and mercurated derivatives of thimerosal" @default.
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- W1975111202 doi "https://doi.org/10.1039/b823467a" @default.
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