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- W1975125457 abstract "Photo-induced reduction of Cu2+ ion by organic electron donors was studied, main attention being paid to the decay kinetics of the cationized donor using two kinds of Cu2+ ions; one is free to move around the micellar surface of copper(II) dodecyl sulfate(Cu(DS)2), the other being fixed in a cyclic polyamine, Cu2+ complex of 2-tetradecyl-1,4,7,10-tetraazacyclododecane (CPA). Sodium 12-(10-phenothiazinyl)dodecanesulfonate (PTHDS) functions quite similarly to N-methylphenothiazine (MPTH) in an electron transfer reaction in Cu(DS)2 micelles, and the reduced Cu+ is ejected from the micelles. In the MPTH–CPA system, MPTH+ is completely ejected from the host micelle in the CPA micellar system. In consequence, the decay of the cationized donor obeys a second-order rate law, while the rate constant becomes much less. In PTHDS–CPA micellar system, on the other hand, the kinetics of the cationized donor is a superposition of two first-order decays of different rate constants, which suggests that the cationized dono..." @default.
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- W1975125457 date "1981-11-01" @default.
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- W1975125457 title "Mechanisms of Light-initiated Redox Reactions of Copper(II)–Cyclic Polyamine Surfactant Assemblies" @default.
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