FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1975137007> ?p ?o ?g. }

• W1975137007 endingPage "1619" @default.
• W1975137007 startingPage "1612" @default.
• W1975137007 abstract "Good quality highly stable copper organosol has been synthesized in a nonhydrolytic approach from the single phase reduction of the precursor Cu(II) stearate by sodium borohydride in toluene under nitrogen gas atmosphere. Surface modification of the synthesized copper organosol with an amino acid, l-cysteine and an alkanethiol (1-dodecanethiol, DDT) is accomplished by the thiolate bond formation between the ligands and the nanoparticle surface. Cysteine molecule binds the copper surface via a thiolate bond and amine linkage but not by the electrostatic interaction with the carboxylate group due to solvent polarity and dielectric medium of the solvent. The synthesized copper particles have been characterized by the optical spectroscopy (UV−vis), electron microscopy (transmission electron microscopy), X-ray photoelectron spectroscopy, and X-ray diffraction. Fourier transform infrared analysis was performed to confirm the surface functionalization of the copper particles either by the amino acid, l-cysteine, or DDT. The synthesized particles are stable for a couple of months without alteration of the spectral profile. After that, the copper particles lead to aggregation via hydrogen bond formation between the amino acid molecules located on the neighboring copper particles. It was found that only DDT (without the need of any reducing agent) could reduce copper stearate to Cu(0) but the synthesized particles remain stable for a week only. It was also observed that the chain length of the alkanethiols does not affect the particle morphology remarkably but has a bearing on the stability of the evolved particles. Furthermore, the synthesized copper particles have been found to serve as an effective catalyst for the synthesis of octlyphenyl ether under nitrogen gas atmosphere." @default.
• W1975137007 created "2016-06-24" @default.
• W1975137007 creator A5002309059 @default.
• W1975137007 creator A5013387421 @default.
• W1975137007 creator A5013634603 @default.
• W1975137007 creator A5040498549 @default.
• W1975137007 creator A5053866339 @default.
• W1975137007 creator A5067628877 @default.
• W1975137007 creator A5070815924 @default.
• W1975137007 creator A5070948768 @default.
• W1975137007 creator A5074708708 @default.
• W1975137007 date "2007-01-09" @default.
• W1975137007 modified "2023-10-16" @default.
• W1975137007 title "Nonaqueous Route for the Synthesis of Copper Organosol from Copper Stearate: An Effective Catalyst for the Synthesis of Octylphenyl Ether" @default.
• W1975137007 cites W1634899121 @default.
• W1975137007 cites W1963907269 @default.
• W1975137007 cites W1968044889 @default.
• W1975137007 cites W1969468762 @default.
• W1975137007 cites W1969785470 @default.
• W1975137007 cites W1971358984 @default.
• W1975137007 cites W1974800704 @default.
• W1975137007 cites W1975586641 @default.
• W1975137007 cites W1976846505 @default.
• W1975137007 cites W1977654606 @default.
• W1975137007 cites W1984771126 @default.
• W1975137007 cites W1989867115 @default.
• W1975137007 cites W1991031733 @default.
• W1975137007 cites W1991060282 @default.
• W1975137007 cites W1991824447 @default.
• W1975137007 cites W1997140350 @default.
• W1975137007 cites W1999702032 @default.
• W1975137007 cites W2004181017 @default.
• W1975137007 cites W2009981131 @default.
• W1975137007 cites W2022190942 @default.
• W1975137007 cites W2027368014 @default.
• W1975137007 cites W2028319584 @default.
• W1975137007 cites W2029990895 @default.
• W1975137007 cites W2031654107 @default.
• W1975137007 cites W2033096857 @default.
• W1975137007 cites W2035884599 @default.
• W1975137007 cites W2036255100 @default.
• W1975137007 cites W2048755825 @default.
• W1975137007 cites W2051696918 @default.
• W1975137007 cites W2055192192 @default.
• W1975137007 cites W2055566080 @default.
• W1975137007 cites W2055941701 @default.
• W1975137007 cites W2057497198 @default.
• W1975137007 cites W2058009528 @default.
• W1975137007 cites W2060149315 @default.
• W1975137007 cites W2067190797 @default.
• W1975137007 cites W2067901272 @default.
• W1975137007 cites W2074356797 @default.
• W1975137007 cites W2074452951 @default.
• W1975137007 cites W2075367213 @default.
• W1975137007 cites W2077645311 @default.
• W1975137007 cites W2077951988 @default.
• W1975137007 cites W2080984985 @default.
• W1975137007 cites W2082514173 @default.
• W1975137007 cites W2088987959 @default.
• W1975137007 cites W2090086871 @default.
• W1975137007 cites W2093276943 @default.
• W1975137007 cites W2094355837 @default.
• W1975137007 cites W2094598119 @default.
• W1975137007 cites W2098622622 @default.
• W1975137007 cites W2101130956 @default.
• W1975137007 cites W2102640392 @default.
• W1975137007 cites W2111251615 @default.
• W1975137007 cites W2117895701 @default.
• W1975137007 cites W2119991142 @default.
• W1975137007 cites W2122727913 @default.
• W1975137007 cites W2123605247 @default.
• W1975137007 cites W2132651708 @default.
• W1975137007 cites W2154113008 @default.
• W1975137007 cites W2324444405 @default.
• W1975137007 cites W2951705220 @default.
• W1975137007 cites W4234612215 @default.
• W1975137007 doi "https://doi.org/10.1021/jp0659711" @default.
• W1975137007 hasPublicationYear "2007" @default.
• W1975137007 type Work @default.
• W1975137007 sameAs 1975137007 @default.
• W1975137007 citedByCount "17" @default.
• W1975137007 countsByYear W19751370072012 @default.
• W1975137007 countsByYear W19751370072014 @default.
• W1975137007 countsByYear W19751370072016 @default.
• W1975137007 countsByYear W19751370072021 @default.
• W1975137007 countsByYear W19751370072022 @default.
• W1975137007 crossrefType "journal-article" @default.
• W1975137007 hasAuthorship W1975137007A5002309059 @default.
• W1975137007 hasAuthorship W1975137007A5013387421 @default.
• W1975137007 hasAuthorship W1975137007A5013634603 @default.
• W1975137007 hasAuthorship W1975137007A5040498549 @default.
• W1975137007 hasAuthorship W1975137007A5053866339 @default.
• W1975137007 hasAuthorship W1975137007A5067628877 @default.
• W1975137007 hasAuthorship W1975137007A5070815924 @default.
• W1975137007 hasAuthorship W1975137007A5070948768 @default.
• W1975137007 hasAuthorship W1975137007A5074708708 @default.
• W1975137007 hasConcept C161790260 @default.
• W1975137007 hasConcept C178790620 @default.

• next