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• W1975161139 startingPage "741" @default.
• W1975161139 abstract "The photophysical properties of [Re(CO)(3)(dppz)(py)](+) (dppz = dipyrido-[3,2-a:2',3'-c] phenazine) and its 11,12 substituted derivatives [Re(CO)(3)(dppzMe(2))(py)](+) and [Re(CO)(3)(dppzF(2))(py)](+) have been examined in organic and aqueous environments using phosphorescence and picosecond transient visible and infrared absorption spectroscopic methods. The roles of the intraligand IL(pi-pi*) and metal-to-ligand charge transfer MLCT(phz) excited states are evaluated and used to explain the major effect of difluoro-substitution, which is particularly remarkable in water, where the excited state of [Re(CO)(3)(dppzF(2))(py)](+) is strongly quenched." @default.
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• W1975161139 date "2007-07-01" @default.
• W1975161139 modified "2023-09-26" @default.
• W1975161139 title "Solvent dependent photophysics of fac-[Re(CO)3(11,12-X2dppz)(py)]+ (X = H, F or Me)" @default.
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• W1975161139 doi "https://doi.org/10.1039/b618651c" @default.
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