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- W1975161665 abstract "The 3A2(nπ*)→1A1X (T1→S0) phosphorescence excitation spectrum of jet-cooled xanthione was investigated in the region 14 920–17 600 cm−1. The structure observed is shown to be due to the T1←S0 absorption and an assignment in terms of the vibronic structure of that band is proposed. A previous assignment of the S1←S0 origin is considered in detail and the transition involved is shown to be most probably due to absorption of a vibronic triplet state T1z,ν7. An alternative but tentative assignment of the S1,0←S0,0 transition is suggested. Comparison is made with previous spectroscopic and theoretical work on the molecule and its congeners, 4H-pyran-4-thione and 4H-1-benzopyran-4-thione." @default.
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- W1975161665 date "2002-11-01" @default.
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- W1975161665 title "The Phosphorescence Excitation Spectrum of Jet-Cooled Xanthione in the Region of the T1←S0 and S1←S0 Absorption Transitions" @default.
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- W1975161665 doi "https://doi.org/10.1006/jmsp.2002.8684" @default.
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